Crystallography of complex thermoelectrics

Correlated thermoelectrics

In the first part of these lecture notes we introduce the phenomenological equations for describing the heat and charge transport in thermoelectric samples. We discuss the solution obtained for various boundary conditions that are appropriate for the homogeneous and inhomogeneous thermoelectrics. In the second part we develop the formalism for a linear-response many-body description of the tran...

Ligand complex structures in protein crystallography

Nanostructured Interfaces for Thermoelectrics

Temperature drops at the interfaces between thermoelectric materials and the heat source and sink reduce the overall efficiency of thermoelectric systems. Nanostructured interfaces based on vertically aligned carbon nanotubes (CNTs) promise the combination of mechanical compliance and high thermal conductance required for thermoelectric modules, which are subjected to severe thermomechanical st...

2005 International Conference on Thermoelectrics

The structure of the thermoelectric Zn4Sb3 is refined using synchrotron X-ray powder diffraction data collected at wavelengths both near to and relatively far from the Zn adsorption edge. In agreement with earlier studies, the compound crystallized in a trigonal structure, space group R3c with a = 12.2406(3)Å, c = 12.4361(3)Å at room temperature, and there are three primary sites in the asymmet...

Thermoelectrics. Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics.

The widespread use of thermoelectric technology is constrained by a relatively low conversion efficiency of the bulk alloys, which is evaluated in terms of a dimensionless figure of merit (zT). The zT of bulk alloys can be improved by reducing lattice thermal conductivity through grain boundary and point-defect scattering, which target low- and high-frequency phonons. Dense dislocation arrays f...